Search results for "Nitrile rubber"
showing 6 items of 6 documents
Einfluss des polymerrückgrats auf eigenschaften von thermoplastischen elastomeren
1992
4-Urazoyl benzoic acid groups were statistically attached to various hydrocarbon elastomers, polar elastomers and partially crystalline polymers via a polymer-analogous reaction. DSC, FTIR, stress-strain experiments and dynamic-mechanical analysis were used to analyse whether these systems, analogous to functionalized polybutadienes, would form ordered supra-molecular structures of the polar side-groups that would lead to a thermoreversible crosslinking. While the structure formation is suppressed for elastomers with a large cross-sectional area of the chain (e.g. butyl rubber) or polar side-groups, (e.g. polychloroprene), the mechanical propertie can be controlled by balancing supermolecul…
Study of methyl methacrylate polymerization in the presence of rubbers
2001
Grafting of poly(methylmethacrylate) onto various unsaturated rubbers is described. The grafting is achieved through thermally initiated methylmethacrylate in-situ polymerization. The main features of the polymerization process, i.e. conversion vs. time, grafting to rubber and gel percentage, have been investigated. The chemical structure of the rubber influences the process: rubber with pendant unsaturations gives rise to higher level of grafting.
Effect of CTBN rubber inclusions on the curing kinetic of DGEBA–DGEBF epoxy resin
2003
Abstract The curing kinetics of an epoxy resin matrix, based on diglycil ether of bisphenol A and F (DGEBA–DGEBF), associated with an anhydride hardener, at different carboxyl-terminated copolymer of butadiene and acrylonitrile liquid rubber (CTBN) concentration (0–10 phr) are studied using a differential scanning calorimetry (DSC) and a stress-controlled rheometer in isothermal and dynamic conditions. The aim of this work is to correlate the presence of the rubber phase with the transition phenomena that occur during the curing process. The CTBN rubber induces a catalytic effect on the polymerization of the pure resin clearly observed by a significant enhancement of the curing rate. Calori…
The influence of the rubber carboxyl functionality on the processability and properties of solid rubber modified epoxy mixtures
2005
A high molecular weight, carboxyl functionalised solid rubber was added to an epoxy resin-aromatic amino system developed for autoclave curing of honeycomb core composite structures. The achievement of an optimal balance of viscous flow and viscoelasticity of the resin, by controlling the nature and extent of cross-linking of the functionalised rubber, was proposed as a route to void-free honeycomb skins. The aim of the present investigation is to understand how the concentration of carboxylic groups of the rubber, prereacted with one of the epoxy monomers, affects the matrix resin flow properties. The concentration of carboxyl groups was changed by reacting them with a monofunctional epoxy…
TI: Compatibilization of PA6/rubber blends by using an oxazoline functionalized rubber
2003
The compatibilization of blends of polyamide 6 with a nitrile butadiene rubber has been investigated. The procedure consists of two steps: modification of the nitrile groups of the rubber into oxazoline in the melt through condensation of ethanolamine with formation of a molecule of ammonia, followed by use of the modified rubber as a compatibilizing precursor which is melt mixed with the polyamide to produce the compatibilized blend. The modification reaction has been detected by NMR analysis and a rheological, mechanical and thermomechanical characterization has been carried out on the all the blends. The results indicate that the modification reaction occurs but the conversion of nitrile…
Gas Barrier, Rheological and Mechanical Properties of Immiscible Natural Rubber/Acrylonitrile Butadiene Rubber/Organoclay (NR/NBR/Organoclay) Blend N…
2020
In this paper, gas permeability studies were performed on materials based on natural rubber/acrylonitrile butadiene rubber blends and nanoclay incorporated blend systems. The properties of natural rubber (NR)/nitrile rubber (NBR)/nanoclay nanocomposites, with a particular focus on gas permeability, are presented. The measurements of the barrier properties were assessed using two different gases—O2 and CO2—by taking in account the blend composition, the filler loading and the nature of the gas molecules. The obtained data showed that the permeability of gas transport was strongly affected by: (i) the blend composition—it was observed that the increase in acrylonitrile butadiene rubber compon…